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111.
Ternary Ti-Al-Nb elemental powder blends with minor addition of SiC were synthesized in a high energy ball mill in order to understand the structural evolution during mechanical alloying (MA) and subsequent thermal treatment. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) techniques were employed to study the structural development during MA. Ti-48%Al-4%Nb-3%SiC and Ti-48%Al-8%Nb-3%SiC blends milled to 20 h were subjected to thermal treatment at 750 °C for 1 h in vacuum. Repeated cold welding and fracturing events of MA resulted in nanocrystalline structure with supersaturated solid solution and amorphous phase. The powder particles were also refined to submicron size due to high energy collision. The nanocrystalline supersaturated solid solution evolved by MA was sustained for prolonged milling time. There was no evidence of intermetallics formation even after early solid solubility extension and formation of nanocrystalline structure. However, nanostructured TiAl and Ti3Al intermetallic compounds were observed after giving thermal treatment to MA powder blend. Since their surface area and energy were enhanced to a great extent, the dispersed ceramic particles reacted with titanium and formed nanosilicide particles. 相似文献
112.
M. Guerioune Y. Amiour W. Bounour O. Guellati A. Benaldjia A. Amara N. E. Chakri M. Ali-Rachedi D. Vrel 《International Journal of Self-Propagating High-Temperature Synthesis》2008,17(1):41-48
Aiming at preparation of shape memory alloys (SMAs), we explored the SHS of Cu1 − x
Zn1 − y
Al1 − z
alloys (0.29 < x < 0.30, 0.74 < y < 0.75, and 0.83 < z < 0.96). The most pronounced shape memory effect was exhibited by the alloys of the following compositions (wt %): (1) Cu(70.6)Zn(25.4)Al(4.0),
(2) Cu(70.1)Zn(25.9)Al(4.0), and (3) Cu(69.9)Zn(26.1)Al(4.0). The effect of process parameters on the synthesis of CuZnAl
alloys was studied by XRD, optical microscopy, and scanning electron microscopy (SEM). The grain size of CuZnAl was found
to depend on the relative amount of the primary CuZn and AlZn phases. Changes in the transformation temperature and heat of
transformation are discussed in terms of ignition intensity and compaction. Mechanism of the process depends on the level
of the temperature attained relative to the melting point of components. At the melting point of AlZn, the process is controlled
by the solid-state diffusion of AlZn into a product layer. The ignition temperature for this system depends on the temperature
of the austenite-martensite transformation in CuZnAl alloys. The composition and structure of the products was found to markedly
depend on process parameters. The SHS technique has been successfully used to prepare a variety of SMAs.
相似文献
113.
The contribution of an oil phase to the agglomeration mechanisms of food powders was evaluated. Maltodextrin (DE 10), palm oil stearin and two palm oil oleins (up to 25% dry mass) were used as food models. Granulation runs were carried out in a pilot plant steam jet agglomerator. The powders containing oleins were more cohesive than those with stearin and the presence of oil changed the agglomeration mechanisms. The size increase mechanism of pure maltodextrin powder was controlled by surface plasticization and agglomerates with suitable instant properties were obtained. Small amount of oil degenerated drastically the rate of dispersion in water of the powders and their agglomerates but the average size and the mechanical resistance of the agglomerates increased when the oil content of the powders increased. SEM micrographs of agglomerates indicated that higher lipid content in the powders produced compact granules, favoring sinkability but hindering their disintegration. Agglomeration enhanced considerably the flowability of the particles containing oil. The dispersion behavior of the powders with higher lipid content could be correlated with the Hausner Number. A pre-agglomeration step favored the blend of the more cohesive powders producing larger and more resistant agglomerates. 相似文献
114.
真空相变锅炉低排烟温度设计与低温腐蚀 总被引:2,自引:1,他引:1
真空相变锅炉是否会明显发生烟气低温腐蚀,一直众说不一。文章从锅炉发生低温腐蚀的机理人手,通过理论分析计算并通过实践检验,提出了真空相变锅炉虽然不能完全避免低温腐蚀问题,但不论排烟温度是否高于烟气露点,低温腐蚀的程度都很弱的观点;给出了真空相变锅炉沿烟气流程金属壁面的腐蚀速度与壁面温度的关系曲线,和烟气温度低于酸露点时金属壁面的腐蚀速度与壁面温度的关系曲线;同时,文章推荐真空相变锅炉的设计排烟温度取130℃左右的低排烟温度。根据上述观点设计的数百台产品已经过多年实际运行,未发现明显 相似文献
115.
松辽盆地南部岩性圈闭识别技术及效果 总被引:1,自引:0,他引:1
寻找隐蔽油气藏一直是油气勘探中的难题,我国东部吉林油田的中浅层已进入高成熟勘探阶段,油气勘探已由早期的构造圈闭勘探转变为现今的以隐蔽圈闭勘探为主的阶段。本文针对松辽盆地南部的西部前缘带三维连片工区及伊通地堑岔路河断陷,综合应用构造精细解释、声波曲线重构波阻抗反演、层序地层学、地震相及沉积(微)相分析、模型正演、地震属性分析、频谱分解及三维可视化等技术手段,所提供的多口探井获得工业油气流或有良好的油气显示,取得了较好的解释效果。 相似文献
116.
Jean‐Marc Aldric Philippe Thonart 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(10):1401-1408
BACKGROUND: In the framework of biological processes used for waste gas treatment, the impact of the inoculum size on the start‐up performance needs to be better evaluated. Moreover, only a few studies have investigated the behaviour of elimination capacity and biomass viability in a two‐phase partitioning bioreactor (TPPB) used for waste gas treatment. Lastly, the impact of ethanol as a co‐substrate remains misunderstood. RESULTS: Firstly, no benefit of inoculation with a high cellular density (>1.5 g L?1) was observed in terms of start‐up performance. Secondly, the TPPB was monitored for 38 days to characterise its behaviour under several operational conditions. The removal efficiency remained above 63% for an inlet concentration of 7 g isopropylbenzene (IPB) m?3 and at some time points reached 92% during an intermittent loading phase (10 h day?1), corresponding to a mean elimination capacity of 4 × 10?3 g L?1 min?1 (240 g m?3 h?1) for a mean IPB inlet load of 6.19 × 10?3 g L?1 min?1 (390 g m?3 h?1). Under continuous IPB loading, the performance of the TPPB declined, but the period of biomass acclimatisation to this operational condition was shorter than 5 days. The biomass grew to approximately 10 g L?1 but the cellular viability changed greatly during the experiment, suggesting an endorespiration phenomenon in the bioreactor. It was also shown that simultaneous degradation of IPB and ethanol occurred, suggesting that ethanol improves the biodegradation process without causing oxygen depletion. CONCLUSION: A water/silicone oil TPPB with ethanol as co‐substrate allowed the removal of a high inlet load of IPB during an experiment lasting 38 days. Copyright © 2008 Society of Chemical Industry 相似文献
117.
In this work, the kinetics and mechanism of free-radical polymerisation of glycidyl methacrylate (GMA) using potassium peroxydisulphate
(PDS) as water soluble initiator in the presence of synthesized 1, 4-Bis (tributyl methyl ammonium) benzene dichloride (TBMABDC)
as multi-site phase transfer catalyst (MPTC) was studied. The polymerisation reactions were carried out under inert and unstirred
conditions at constant temperature of 60 ± 1°C in cyclohexane/water biphase media. The role of concentrations of monomer,
initiator, catalyst and volume fraction of aqueous phase, solvent polarity and temperature on the rate of polymerisation (Rp)
was ascertained. The order with respect to monomer and initiator was found to be unity. The order with respect to catalyst
was found to be 0.51. The rate of polymerisation is independent of ionic strength and pH of the medium. However, an increase
in the polarity of solvent has slightly increased the Rp value. Based on the results obtained, a suitable kinetic scheme has
been proposed to account for the experimental observations and its significance discussed. 相似文献
118.
119.
横向各向同性介质中的初至波旅行时计算 总被引:1,自引:0,他引:1
本文直接采用Thomsen导出的横向各向同性介质中的相速度、群角与相角、群速度与相速度的精确函数关系,提出了一种新的具有任意各向异性强度的横向各向同性介质中的初至波旅行时计算方法,它不同于Faria等人给出的采用群速度近似公式(Byun)的仅适应弱各向异性的初至波旅行时计算方法。该新算法在计算具有任意各向异性强度的横向各向同性介质中的初至波旅行时时,并不显著地增大计算时间。分析对比由新算法得到的初至波旅行时的等值线图和由交错网格有限差分波场模拟得到的波场快照表明,无论是对弱各向异性还是对强弱各向异性,新算法都具有较高的精度;随着各向异性强度的增大,新算法的计算结果与采用近似公式计算结果的差值也随之增大。 相似文献
120.
H. Ji J. E. Dolbow 《International journal for numerical methods in engineering》2004,61(14):2508-2535
We consider a problem stemming from recent models of phase transitions in stimulus‐responsive hydrogels, wherein a sharp interface separates swelled and collapsed phases. Extended finite element methods that approximate the local solution with an enriched basis such that the mesh need not explicitly ‘fit’ the interface geometry are emphasized. Attention is focused on the weak enforcement of the normal configurational force balance and various options for evaluating the jump in the normal component of the solute flux at the interface. We show that as the reciprocal interfacial mobility vanishes, it plays the role of a penalty parameter enforcing a pure Dirichlet constraint, eventually triggering oscillations in the interfacial velocity. We also examine alternative formulations employing a Lagrange multiplier to enforce this constraint. It is shown that the most convenient choice of basis for the Lagrange multiplier results in oscillations in the multiplier field and a decrease in accuracy and rate of convergence in local error norms, suggesting a lack of stability in the discrete formulation. Under such conditions, neither the direct evaluation of the gradient of the approximation at the phase interface nor the interpretation of the Lagrange multiplier field provide a robust means to obtain the jump in the normal component of solute flux. Fortunately, the adaptation and use of local, domain‐integral methodologies considerably improves the flux evaluations. Several example problems are presented to compare and contrast the various techniques and methods. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献